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According to the IUPAC rules, locants can be omitted if:
(note that some of these conditions overlap with each other).
Here are some illustrative examples that try to capture these implications of this at this "introductory organic chemistry" level:
ethanol | ![]() |
Locant dropped | unambiguous, all C atoms in the parent chain (ethane) are equivalent |
propene | ![]() |
Locant dropped | unambiguous, C=C must be at the end of the parent chain |
propan-1-ol | ![]() |
Locant can not be dropped | ambiguous, -OH group could be on C1 or C2 of the parent chain (propane) which are different |
propanal | ![]() |
Locant dropped | unambiguous, an aldehyde must be at the end of the chain which defines C1 |
propan-2-one | ![]() |
Locant can not be dropped | Ketones aren't restricted to ends of chains and the parent chain (propane) has two different positions. (IUPAC specifically cites this example) |
cyclohexanol | ![]() |
Locant dropped | unambiguous, all positions on the parent ring (cyclohexane) are equivalent |
butan-2-one |
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Locant can not be dropped | Ketones aren't restricted to ends of chains and the parent chain (butane) has two different positions (IUPAC specifically cites this example) |
2-chloroethan-1-ol | ![]() |
Locants can not be dropped | View ethanol as the parent, then there are two places the substituent could be and therefore required to include both locants. (IUPAC specifically cites this example) |
cyclohexane-1,2-diol | ![]() |
Locants can not be dropped | With two groups on a cyclic structure both locants are required according to the IUPAC rules to distinguish 1,1-, 1,2-, 1,3- etc. |
prop-2-en-1-ol | ![]() |
Locants can not be dropped | With two groups on parent structure both locants are required according to the IUPAC rules to distinguish 1,1- & 1,2-. |
cyclohex-2-en-1-ol | ![]() |
Locants can not be dropped | With two groups on a cyclic structure both locants are required according to the IUPAC rules to distinguish 1,1-, 1,3-, 1,4- etc. |
3-bromocyclohex-1-ene | ![]() |
Locants can not be dropped | With two groups on a cyclic structure both locants are required according to the IUPAC rules to distinguish 1,1-, 1,3-, 1,4- etc. (IUPAC specifically cites this example) |
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©Dr. Ian Hunt, Department of Chemistry | ![]() |