Useful Concepts |
This section contains the basic IUPAC rules for nomenclature and a table of functional groups in priority order, with examples.
For a complete introduction to organic nomenclature : Basic IUPAC Organic Nomenclature
Naming branched chain alkanes (the IUPAC way....)
Here is a list of the root names for the hydrocarbon chains of C1 to C12 and a few other biologically important chains:
Here is a list of important functional groups arranged in
decreasing priority order. All the structures can be manipulated using JMOL
This priority order is important in nomenclature as the higher priority
group is the principle functional group and it is typically numbered
such that is has the lowest number (the locant).
You need to learn
to recognise these functional groups not just for nomenclature but in
order to recognise their reactions later.
In each case the fundamental functional group unit is shown, it is this
that you need to be able to recognise - pay attention to the atoms
involved and the bonding patterns.
Functional |
Formula |
Structure |
Carboxylic Acids
|
|
|
Acid Anhydrides
|
||
Esters
|
|
|
Acyl Halides
|
|
|
Amides
|
||
Nitriles
|
||
Aldehydes
|
||
Ketones
|
||
Alcohols
|
||
Thiols
|
||
Amines
|
||
Ethers
|
||
Sulfides
|
|
|
Alkenes
|
||
Alkynes
|
||
Alkyl Halides
|
||
Nitro
|
||
Alkanes
|
© Dr. Ian Hunt, Department of Chemistry, University of Calgary |